aluminium phosphide formula
November 13th, 2020

AlP crystallizes in the cubic zinc blende motif, wherein all atoms have tetrahedral coordination. It is used to kill small verminous mammals such as moles, rabbits, and rodents. After ingestion metal phosphides may be hydrolysed to produce phosphine, which may be absorbed in the gastro-intestinal tract [38–40]. It has been a substantial problem in the Indian subcontinent. 57.95 Molecular Formula. Liver damage may develop in patients who survive for longer periods. Ramesh C. Gupta, James W. Crissman, in Haschek and Rousseaux's Handbook of Toxicologic Pathology (Third Edition), 2013. Two children and 29 of 31 crew members aboard a grain freighter became acutely ill after inhaling phosphine originating from aluminum phosphide. Zinc phosphide and aluminum phosphide both release phosphine gas when they come in contact with the acidic contents of the stomach. CDC is not responsible for Section 508 compliance (accessibility) on other federal or private website. [3], Categories: Aluminium compounds | Phosphides | Semiconductor materials | Inorganic insecticides | III-V compounds. investigated the efficiency of PDT with 0.01% MB as PS and an indium–gallium–aluminum phosphide low-level laser (660 nm) as the light source. There is no effective antidote available, and the incidence of death secondary to exposure has been increasing Phosphine inhibits mitochondrial cytochrome oxidase. In man this cumulative effect is not proven [44]. d. This colorless solid is generally sold as a grey-green-yellow powder due to the presence … Copyright © 2020 Elsevier B.V. or its licensors or contributors. counts. Related materials crystallize similarly, including GaAs. © 1997-2020 LUMITOS AG, All rights reserved, https://www.chemeurope.com/en/encyclopedia/Aluminium_phosphide.html, Your browser is not current. No significant absorption can be observed following skin exposure. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B978012386454300467X, URL: https://www.sciencedirect.com/science/article/pii/B9780123694133500720, URL: https://www.sciencedirect.com/science/article/pii/S0378608016300253, URL: https://www.sciencedirect.com/science/article/pii/B9780123743671000288, URL: https://www.sciencedirect.com/science/article/pii/B9780444815576500241, URL: https://www.sciencedirect.com/science/article/pii/B9780123864543001846, URL: https://www.sciencedirect.com/science/article/pii/B978032346152800010X, URL: https://www.sciencedirect.com/science/article/pii/B978012415759000042X, URL: https://www.sciencedirect.com/science/article/pii/B9780128000342003657, URL: https://www.sciencedirect.com/science/article/pii/B9780123744845000389, Encyclopedia of Toxicology (Third Edition), Handbook on the Toxicology of Metals (Third Edition), A Worldwide Yearly Survey of New Data in Adverse Drug Reactions, Lauren K. Roller, Laura J. Baumgartner, in, The Regulatory Evaluation of the Skin Effects of Pesticides, Hayes' Handbook of Pesticide Toxicology (Third Edition), Antimicrobial Photodynamic Therapy With Nanoparticles Versus Conventional Photosensitizer in Oral Diseases, Reza Fekrazad, ... Katayoun A.M. Kalhori, in, , Guglielmi Cde et al. Aluminum phosphide. By continuing you agree to the use of cookies. Phosphine is a colourless gas at room temperature and normal atmospheric pressure. To use all the functions on Chemie.DE please activate JavaScript. Aluminum phosphide has been used for suicide and has caused accidental deaths to fumigators in several countries, including the US and Saudi Arabia. Crude aluminium phosphide can be prepared in the laboratory by igniting a mixture of red phosphorus and powdered aluminium. aluminium gallium indium phosphide). However, it is still used in certain countries to help protect stored grains from pets and rodents. One of the children died (Wilson et al., 1980). Samples must be submitted frozen in air-tight containers for analysis of phosphine. They concluded that PDT using AlClPc-cationic liposomes is an effective and also clinically safe approach to attenuate the bacterial count in caries. *Please select more than one item to compare. Aluminum Acetate is an astringent. Celphos, Fumitoxin, Phostoxin, and Quick Phos. RTECS # BD1400000 CAS # 20859-73-8; 1302-45-0; 71751-04-7 See: NMAM or OSHA Methods. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE. Phosphine is denser than air. Related Pages. Toxic myocarditis is a poorly defined entity that is generally diagnosed clinically in patients with serologic and electrocardiographic signs of myocarditis and recent toxic exposure. The acid in the digestive system of the rodent reacts with the phosphide to generate the toxic phosphine gas. This colourless solid is generally sold as a grey-green-yellow powder due to the presence of impurities arising hydrolysis and oxidation. AlP Synonyms. Deaths have occurred in animals as a result of repeated daily exposures to concentrations below acutely injurious concentrations [42,43]. Other pesticides similar to aluminium phosphide are zinc phosphide and calcium phosphide. [1], Aluminium phosphide reacts with water or acids to release phosphine.[2]. You will be subject to the destination website's privacy policy when you follow the link. FUMITOXIN® tablets and pellets contain 56% aluminum phosphide, allowing for the controlled release of phosphine gas. Aluminium phosphide is a highly toxic inorganic compound with the chemical formula AlP used as a wideband gap semiconductor and a fumigant. Magnesium and aluminium phosphide are used for fumigation in pest control, and zinc phosphide as a rodenticide. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. The National Institute for Occupational Safety and Health immediately dangerous to life or health value for phosphine is 50 ppm. Encyclopedia of Forensic and Legal Medicine (Second Edition), Handbook of Toxicology of Chemical Warfare Agents, Zinc toxicosis results from ingestion of bait containing this compound or by eating tissues of zinc phosphide-poisoned animals. Aluminum phosphide (AlP) is a highly effective outdoor and indoor insecticide and rodenticide. Aluminum phosphide is a well-known insecticide that has been banned in several countries due to its high fatality rate. Industrially, AlP is a semiconductor material that is usually alloyed with other binary materials for applications in devices such as light-emitting diodes (e.g. Impurities with diphosphine (P2H4) in air can be explosive at room temperature. They compared PDT with the conventional drilling method in removing cariogenic bacteria in deep carious lesions. This material is a wide band gap semiconductor and is used as a fumigant. While baits incorporating zinc phosphide are the primary formulation for killing rodents, the occupational exposure of fumigators to phosphine gas has caused a number of fatal incidents. Currently there are 23 products containing aluminum phosphide … Although the registrant’s name was changed subsequently, the original U.S. aluminum phosphide registration remains active. Used for fumigation of grain, grain products, oilseeds and dried potatoes. July 2016 Molecular Weight. Histopathological findings in the kidneys include renal tubular degeneration and necrosis (Casteel and Bailey, 1986). Zinc toxicosis results from ingestion of bait containing this compound or by eating tissues of zinc phosphide-poisoned animals. Acute Exposure Guideline Level (the airborne concentration of a substance above which it is predicted that the general population, including susceptible individuals, could experience irreversible or other serious, long-lasting adverse health effects or an impaired ability to escape) for up to 8 h is 0.25 ppm. Fumitoxin® is available in several package sizes designed to meet your fumigant needs. Advanced Search | Structure Search. Michael O’Malley, in Hayes' Handbook of Pesticide Toxicology (Third Edition), 2010, Aluminum phosphide: Formula, AlP; MW, 57.95; MP, 2550°C; log P, NA; VP, negligible; solubility in H2O, decomposes in water; other physical properties: must be protected from moist air because it reacts readily to produce phosphine. Takotsubo cardiomyopathy is a form of exaggerated catecholamine-induced injury caused by stress, and results in acute heart failure, although sudden death has yet to be reported.

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